PostgreSQL + WAL-E + Cloudfiles = Awesome
Instead of just using a simple socket to communicate, WAL-E sends these base backups and WAL files across the internet with the help of a cloud object store, like Cloudfiles (or any OpenStack Swift deployment). This gives you the advantage that, in addition to just being replication, you have a durable backup of your database for disaster recovery. Further, you have effectively infinite read scalability from the archives, you can keep adding more followers without putting more stress on the leader.